A buffer is prepared by mixing 204.0 mL of 0.452 M HCl and 0.500 L of 0.400 M sodium acetate (NaC2H3O2):
Calculate the pH of the buffer.
How many grams of KOH must be added to 0.500 L of the buffer to change the pH by 0.15 units?

Answers

Answer 1

Answer:

pH = 4.89

0.6171g of KOH must be added

Explanation:

Sodium acetate reacts with HCl producing acetic acid as follows:

NaC2H3O2 + HCl → HC2H3O2 + NaCl

That means the moles added of HCl are moles of acetic acid produced and moles of acetate are initial moles - moles of HCl

Moles HCl = Moles acetic acid:

0.204L * (0.452mol / L) = 0.0822 moles acetic acid.

Initial moles sodium acetate:

0.500L * (0.400mol / L) = 0.200 moles

Moles sodium acetate:

0.200 moles - 0.0822 moles = 0.1172 moles sodium acetate

The pH of this buffer (Mixture of a weak acid and its conjugate base) is obtained using H-H equation:

pH = pKa + log [A-] / [HA]

Where pH is pH of the buffer,

pKa is pKa of the buffer (4.74 for acetic acid)

[A-] Moles of sodium acetate -Conjugate base-

And HA moles of acetic acid -Weak acid-

pH = 4.74 + log [0.1172 moles] [0.0822 moles]

pH = 4.89

In 0.500L the moles of the buffer are:

0.500L * (0.200moles / 0.704L) = 0.142 moles of buffer

For a pH of 0.15 units more (4.89 + 0.15 = 5.04):

5.04 = 4.74 + log [Acetate] / [Acetic acid]

0.3 = log [Acetate] / [Acetic acid]

1.9953 = [Acetate] / [Acetic acid] (1)

And as:

0.142 = [Acetate] + [Acetic acid] (2)

Replacing (2) in (1):

1.9953 = 0.142 - [Acetic acid]  / [Acetic acid]

1.9953 [Acetic acid] = 0.142 - [Acetic acid]

2.9953 [Acetic acid] = 0.142 moles

[Acetic acid] = 0.0474 moles of acetic acid must remain after the addition of KOH.

In the beginning, moles of acetic acid are:

0.0822 moles * (0.500L / 0.704L) = 0.0584 moles.

That means moles added of KOH (Equal to moles of acetic acid that react) are:

0.0584 moles - 0.0474 moles = 0.0110 moles of KOH

In grams (Molar mass KOH = 56.1g/mol):

0.0110 moles KOH * (56.1g/mol) =

0.6171g of KOH must be added

Related Questions

Balance chemical equation hbr(aq)+o2(g) h20(l)+br2(l)

Answers

4HBr(aq) + O2(g)= 2H2O(l) + 2Br2(l)

2. Combining 0.242 mol Fe2O3 with excess carbon produced 10.2 g Fe.

Fe2O3+3C⟶2Fe+3CO

(a) Actual yield of Fe mole

(b) percentage mole

(c) theoretical yield of iron mmoles

Answers

actual yield = 0.182 mole

theoretical yield : 0.484 mole

percentage mole(% yield)=37.6%

Further explanation

Percent yield is the comparison of the amount of product obtained from a reaction with the amount you calculated

General formula:

Percent yield = (Actual yield / theoretical yield )x 100%

An actual yield is the amount of product actually produced by the reaction. A theoretical yield is the amount of product that you calculate from the reaction equation according to the product and reactant coefficients

Reaction

Fe₂O₃+3C⟶2Fe+3CO

a. actual yield of Fe mole

10.2 g produced

[tex]\tt mol~Fe=\dfrac{10.2}{56}=0.182[/tex]

b. percentage mole and theoretical yield

0.242 mol Fe₂O₃ = 2 x 0.242 mol Fe = 0.484 mol (theoretical yield)

percentage yieldpercentage mole)

[tex]\tt \dfrac{0.182}{0.484}=0.376=37.6\%[/tex]

The mass of 900. atoms of sodium(Na)

Answers

Answer:

3.44 × 10⁻²⁰ g Na

General Formulas and Concepts:

Chemistry - Atomic Structure

Reading a Periodic TableUsing Dimensional AnalysisAvogadro's Number - 6.022 × 10²³ atoms, molecules, formula units, etc.

Explanation:

Step 1: Define

900 atoms Na

Step 2: Identify Conversions

Avogadro's Number

Molar Mass of Na - 22.99 g/mol

Step 3: Convert

[tex]900 \ atoms \ Na(\frac{1 \ mol \ Na}{6.022 \cdot 10^{23} \ atoms \ Na} )(\frac{22.99 \ g \ Na}{1 \ mol \ Na} )[/tex] = 3.4359 × 10⁻²⁰ g Na

Step 4: Check

We are given 3 sig figs. Follow sig fig rules and round.

3.4359 × 10⁻²⁰ g Na ≈ 3.44 × 10⁻²⁰ g Na

Which of the following descriptions best describes a weak base?

A. a base that dissociated completely in water

B. a base that generates a lot of hydroxide ions in water

C. a base that has very low concentration in water

D. A base that dissociates only slightly in water

Answers

Answer:

umm.. B. a base that generates a lot of hydroxide ions in water.

The descriptions best describes a weak base is a base that dissociates only slightly in water.

What are bases?

Bases are those substances which react with acids to neutralize them, generally bases are the compounds of oxides, hydroxides and carbonates of metal elements.

Bases shows dissocation in the aqueous soluition and pH of bases ranges from 7 to 14. Strong bases shows full dissociation into ions and having higher pH values and weak bases shows partial dissociation into ions & having lower pH values.

Hence, option (D) is correct.

To know more about bases, visit the below link:

https://brainly.com/question/3920636

how does mass and volume affect sinking and floating? Please don't plagiarize.... ​

Answers

Answer:

If an object has a higher density than the fluid it is in (fluid can mean liquid or gas), it will sink. If it has a lower density, it will float. Density is determined by an object's mass and volume. If two objects take up the same volume, but have one has more mass, then it also has a higher density.

Explanation:

An electron in the first energy level of the electron cloud has
an electron in the third energy level.

Answers

Answer: A LOWER ENERGY

Explanation:

did the test

Answer:

A lower energy!

Explanation:

I know this is not much of an explanation but I took the test i hope you have an amazing day afternoon or night! Hope this helps :3

Please help me please it due today at 11:00am plz help me

Answers

Answer:

Point F

Explanation:

Point F is the maximum potential energy.

Point G is lots of kinetic energy.

Point H is low potenital energy and low kinetic energy.

Determine the correct hybridization (from left to right) about each central atom in
CH3CH2OH.
A) 1st C sp3 ; 2nd C sp2 ; O sp B) 1st C sp3 ; 2nd C sp3 ; O sp3
C) 1st C sp ; 2nd C sp2 ; O sp3 D) 1st C sp3 ; 2nd C sp2 ; O sp2

Answers

Answer:

B) 1st C sp3 ; 2nd C sp3 ; O sp3

Explanation:

Both carbons in ethanol have an sp³ configuration of their orbitals, given that each carbon atom binds to four other atoms, as can be seen on the extended formula in the attachment.

In these carbons (1st and 2nd) one s orbital and three p orbitals are hybridized to form four hybrid orbitals sp³. These orbitals form four bonds and their bond angles are close to the tetrahedral value of 109.5º,as can be seen for methanol which also has an sp³ configuration.

The oxygen atom can also be described as having sp³ hybrid orbitals. Two of the four hybrid sp³ orbitals in oxygen are occupied by lone electron pairs, and two are used to form bonds with other atoms (in this case the oxygen is bonded to a carbon atom and a hydrogen atom).

Therefore, the three central atoms have an sp³ configuration.

How much work (in JJ) is required to expand the volume of a pump from 0.0 LL to 2.5 LL against an external pressure of 1.1 atmatm

Answers

Answer:

- 278.85 J  

Explanation:

Given that:

Pressure = 1.1 atm

The initial volume V₁ = 0.0 L

The final volume V₂ = 2.5 L

The work that takes place in a reaction at constant pressure can be expressed by using the equation:

W = P(V₂ - V₁ )

Since the volume of the gas is expanded from 0 to 2.5 L when 1.1 atm pressure is applied. Then, the work can be given by the expression:

W = - P(V₂ - V₁ )

W = -1.1 atm ( 2.5 - 0.0) L

W = -1.1 atm (2.5 L)

W = -2.75 atm L

Recall that:

1 atm L = 101.4 J

Therefore;

-2.75 atm L = ( -2.75 × 101.4 )J

= -278.85 J  

Thus, the work required at the chemical reaction when the pressure applied is 1.1 atm  = - 278.85 J  

A particular reaction has an enthalpy and entropy of reaction of ∆H = +33 kJ/mol and ∆S = +0.15 kJ/mol⋅K. At the three indicated temperatures, determine if either reactants or products are favored?

Answers

Answer:

Explanation:  check my paage

What is the hybridization state on the central N atom in the azide ion, N3−?

Answers

The sp hybridization of the central nitrogen is consistent with the linear structure of the azide ion. In A, the terminal nitrogens may both be sp2 hybridized; after all the drawing looks similar to the double bond in ethylene.

HURRY
Which part of an atom is mostly empty space?
nucleus
proton cloud
electron cloud
neutron

Answers

Answer:

Electron cloud

Explanation:

If you were to scale the size of the atom up to have the nucleus be about the size of a basket ball, then the placement of the actual electrons (about the size of a large marble at this scale) throughout the cloud would be many yards away from the nucleus.

Electron cloud! Good luck!

Explain how the immune system responds to pathegons

Answers

Answer:

The immune system responds to antigens by producing cells that directly attack the pathogen, or by producing special proteins called antibodies. Antibodies attach to an antigen and attract cells that will engulf and destroy the pathogen. The main cells of the immune system are lymphocytes known as B cells and T cells.

Which of the following is an example of a mixture?

A.

calcium

B.

the atmosphere

C.

carbon dioxide

D.

water

Answers

Answer: B. The atmosphere
Explanation: The atmosphere is a mixture of gases, so I think it is the answer.

Answer:

B. the atmosphere

Explanation:

hope it helps

1) If a bottle of olive oil contains 1.3 kg of olive oil, what is the volume, in milliliters, of the olive oil? Express your answer to two significant figures and include the appropriate units. 2) A cannon ball made of iron has a volume of 116 cm^3. What is the mass, in kilograms, of the cannon ball? Express your answer to three significant figures and include the appropriate units. 3) A balloon filled with helium has a volume of 6.1 L. What is the mass, in grams, of helium in the balloon? Express your answer to two significant figures and include the appropriate units.

Answers

Answer:

1) 1.4 × 10³ mL

2) 0.913 kg

3) 1.1 g

Explanation:

1)

Step 1: Calculate the volume of 1.3 kg of olive oil

The density of olive oil is 0.917 kg/L.

1.3 kg × (1 L/0.917 kg) = 1.4 L

Step 2: Convert the volume to mL

We will use the relationship 1 L = 10³ mL.

1.4 L × (10³ mL/1 L) = 1.4 × 10³ mL

2)

Step 1: Calculate the mass of the cannon ball

The density of iron is 7.87 g/cm³.

116 cm³ × 7.87 g/cm³ = 913 g

Step 2: Convert the mass to kg

We will use the relationship 1 kg = 10³ g.

913 g × (1 kg / 10³ g) = 0.913 kg

3)

Step 1: Calculate the mass of the helium in the balloon

The density of balloon is 0.18 g/L.

6.1 L × 0.18 g/L = 1.1 g

An object has a mass of 3.50 grams and a density of 5.61 g/mL. What is the volume of this object? *

Answers

Answer:

0.62 mL

Explanation:

The volume of a substance when given the density and mass can be found by using the formula

[tex]volume = \frac{mass}{density} \\[/tex]

From the question we have

[tex]volume = \frac{3.50}{5.61} \\ = 0.6238859...[/tex]

We have the final answer as

0.62 mL

Hope this helps you

What elements in group 17 are solids liquids and gass?

Answers

Answer:  \(\left( \ce{F} \right)\), chlorine \(\left( \ce{Cl} \right)\), bromine \(\left( \ce{Cl} \right)\), iodine \(\left( \ce{I} \right)\), and astatine \(\left( \ce{At} \right)\)

Explanation:

Whats the answer 50 points and brainliest if its right

Answers

Answer:

D

Explanation:

A student wants to use cookies to make a model of the genetic makeup of the offspring of asexual reproduction. He has vanilla cookies and chocolate cookies available. How can he make his model?
A.
Put chocolate cookies in a row with arrows between them showing the progression from parent to offspring.
B.
Use one chocolate cookie parent with arrows showing that it produces vanilla cookies and chocolate cookies as offspring.
C.
Use chocolate cookies and vanilla cookies as the parents, and vanilla cookies and chocolate cookies as the offspring.
D.
Use chocolate cookies and vanilla cookies as parents, and combine half a vanilla cookie and half a chocolate cookie for the offspring.

Answers

Answer:

i am not sure but it seems D is the best

Answer:

A

Explanation:

It seems to be the most logical. My reasoning is that for B when it uses one parent cookie that produced genetically different offspring. That is what makes it incorrect. The other two options involve two parents which means that the reproduction would be sexual. A. would be the closest to the answer.

Please let me know if this is correct! Hope it helped.

Which are the three most common gases Giving Brainliest

Answers

Answer:

B

Explanation:

i hope this helps

Ice, H2O(s), is classified as: An ionic compound, a molecular compound, a homogeneous mixture, a heterogeneous mixture

Answers

Answer:

A molecular compound.

Explanation:

An ionic compound is composed of both metal and non-metal elements. Oxygen and hydrogen are both non-metal elements.Any mixture (no matter if it is homogeneous or heterogeneous) is composed of two or more compounds.Ice is simply water in solid form, so it is only one compound. Hence the answer is A molecular compound.

Ice, H2O(s), is classified as ; ( B ) A molecular compound

Given that Ice and H₂O are the same element but in different forms therefore we can classify Ice, H₂O as been a molecular compound.

Ice and H₂O are not ionic compounds because ionic compounds are formed between metal and non-metal elements while H₂O and Ice are neither metals but are both Nonmetals

Hence we can conclude that Ice, H2O(s), is classified as A molecular compound

Learn more : https://brainly.com/question/18158405

Question 1 of 10
In which state of matter do the particles move independently of one another?
A. Amorphous solid
B. Gas
C. Crystalline solid
D. Liquid

Answers

Liquid because objects are all together

Answer:

Gas (B)

Explanation:

a student performed an experiment, using a cocktail peanut, before it was burned the peanut half weighed .353 g. After burning the residue weighed .016 g. The energy released by the conjunction increased the temperature of 200. mL of water in the calorimeter by 7.2 degrees Celsius. Calculate the mass of peanut consumed in the combustion.

Answers

Not sure but it should be on google

2.) Given that the reaction below is a precipitation reaction, what is the missing symbol?
AND
3.) Which of the following would produce a precipitate when mixed water (H20)?

PLZ HELP IM GONNA FAIL THE SEMESTER!!!! I'LL AWARD BRAINLIEST!!

Answers

Answer:

2) (s)

3) PbBr2

Explanation:

2) This is a precipitation rxn which means if forms a solid, We use (s) for solid.

3) Refer to solubility table

The sun shines more directly near the equator, bringing more warmth there. In polar regions the sun shines at angles such that
they get little or no sunlight during the winter, causing colder temperatures. Predict how these differences in temperature create a
movement in the atmospheric gases and distribute heat energy from the sun across the planet.
A)
B)
As air in one region diffuses, it becomes less condensed than the
surrounding air and begins to rise and draws more air along.
As air in one region warms, it becomes less dense than the surrounding air
and begins to rise and draws more air in underneath.
As air in one region warms, it becomes less nebulous than the surrounding
air and begins to descend and draws more air in with it.
As air in one region cools, it becomes less compact than the surrounding
air and begins to accelerate and draws more air in supportively.
C)
D)

Answers

Answer:Because the Earth is round and not flat, the Sun's rays don't fall evenly on the land and oceans. The Sun shines more directly near the equator bringing these areas more warmth. However, the polar regions are at such an angle to the Sun that they get little or no sunlight during the winter, causing colder temperatures.

Explanation:

Which statement is incorrect?
Acids produce H+ ions when ionized.
B. Bases produce OH^ lons when lonized.
C. Bases are found in the pH range of 1-7 on the pH
scale.
Distilled water has a neutral pH of 7.0.

Answers

Answer:

C. Bases are found in the pH range of 1-7 on the pH scale.

Explanation:

Acids are less than 7 on the pH scale, so 1-7. Bases are more than 7 on the pH scale, so 7-14. That's why C is incorrect, hope this helps!

The following concerns the combustion of nitromethane (CH3NO2 - a popular fuel for top-fuel dragsters) according to the reaction below:_______. 2 CH3N02 (1) + ž02(g) → 2C02) + 3H20 (1) + N2(9) a. Burning 121 L of nitromethane at constant pressure releases 1.6 x 100 kJ of energy. What is the enthalpy of combustion of this reaction? The density of nitromethane is 1.16 g/cm². b. Assume you transfer heat involved in the previous problem to 1 kL of water that is initially at 25.0 °C. What is the final temperature of the water?

Answers

Answer:

695.8kJ/mol = Enthalpy of combustion

Final temperature = 407.4°C

Explanation:

Taken the reaction:

2CH₃NO₂ + 3/2 O₂ → 2CO₂ + 3H₂O + N₂

The enthalpy of the reaction is the heat released when 1 mole of nitromethane are in combustion.

We need to find the moles presents in 121L of nitromethane using its density and molar mass (61.04g/mol). As these moles releases 1.6x10⁶kJ, we need to find heat released per mole of nitromethane

Mass nitromethane:

121L = 121000cm³ * (1.16g/cm³) = 140360g

Moles:

140360g * (1mol / 61.04g) = 2299.5 moles of nitromethane

Heat released per mole of nitromethane:

1.6x10⁶kJ / 2299.5 mol = 695.8kJ/mol = Enthalpy of combustion

The symbol - is because the heat is released, a + symbol is when the heat is absorbed.

Using:

Q = m×C×ΔT

Where Q is heat (1.6x10⁶kJ = 1.6x10⁹J)

m is mass of water:

1kL = 1000L = 1x10⁶mL = 1x10⁶g

C is specific heat of water: 4.184J/g°C

And ΔT is change in temperature.

Solving for ΔT:

1.6x10⁹J = 1x10⁶g * 4.184J/g°C * ΔT

ΔT = 382.4°C

As initial temperature was 25°C, final temperature is:

382.4°C + 25°C =

407.4°C

From the following heats of reaction,
2C (graphite) + H2 (g) -->C2H2 (g) H = 227 kJ
6C (graphite) + 3H2 (g) -->C6H6 (l) H = 49 kJ
calculate the heat for the reaction
3C2H2 (g) -->C6H6 (l)
A. 26.7 kJ
B. -26.7 kJ
C. -178 kJ
D. 178 kJ
E. -632 kJ
F. 632 kJ

Answers

Answer:+178

Explanation:

The heat of the reaction for the following reactions is 178 kJ. the correct option is D.

What is the heat of the reaction?

The heat that is added or removed during a chemical reaction is called the heat of reaction.

It is also called the enthalpy of the reaction.

The heat is absorbed or released to maintain the temperature of the reaction.

The enthalpy can be calculated by subtracting the enthalpy of the product from the enthalpy of the reactant.

Thus, the correct option is D.

Learn more about the heat of the reaction

https://brainly.com/question/517776

what is the device to use to measure a potential difference in a circuit called?

Answers

Voltmeter.
would be correct

Answer:

c. Voltmeter

Explanation:

PLATO LIVES MATTER

What is the mass, in grams, of 2.3 moles of gold?

Answers

Answer:

453.031g

Explanation:

atomic mass (molar mass)- 196.97g/m

2.3(196.97)=453.031

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